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cholecalciferol

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cholecalciferol

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Also known as (1S,3Z)-3-[(2E)-2-[(1R,3aS,7aR)-1-[(1R)-1,5-dimethylhexyl]-7a-methyl-2,3,3a,5,6,7-hexahydro-1H-inden-4-ylidene]ethylidene]-4-methylene-cyclohexan-1-ol, oleovitamin D3, (1S,3Z)-3-[(2E)-2-[(1R,3aS,7aR)-7a-methyl-1-[(2R)-6-methylheptan-2-yl]-2,3,3a,5,6,7-hexahydro-1H-inden-4-ylidene]ethylidene]-4-methylidene-cyclohexan-1-ol, (1S,3Z)-3-[(2E)-2-[(1R,3aS,7aR)-7a-methyl-1-[(2R)-6-methylheptan-2-yl]-2,3,3a,5,6,7-hexahydro-1H-inden-4-ylidene]ethylidene]-4-methylidenecyclohexan-1-ol, (1S,3Z)-3-[(2e)-2-[(1R,3AR,7as)-7a-methyl-1-[(2R)-6-methylheptan-2-yl]-2,3,3a,5,6,7-hexahydro-1H-inden-4-ylidene]ethylidene]-4-methylidene-cyclohexan-1-ol, (1S,3Z)-3-{2-[(1R,4E,7aR)-7a-methyl-1-[(2R)-6-methylheptan-2-yl]-octahydro-1H-inden-4-ylidene]ethylidene}-4-methylidenecyclohexan-1-ol, (5Z,7e)-(3S)-9,10-secocholesta-5,7,10(19)-trien-3-ol, 9,10-secocholesta-5,7,10(19)-trien-3beta-ol

Cholecalciferol, also known as vitamin D3, colecalciferol or calciol, is a skin-made vitamin D that is found in certain foods and used as a dietary supplement. It was first described in 1936, and is on the World Health Organization's List of Essential Medicines. In 2023, it was the 68th most commonly prescribed medication in the United States, with more than 9million prescriptions, and is available as a generic medication.

Key facts

Drug.INN
Colecalciferol
Drug.image
Cholecalciferol.svg
Drug.image_class
skin-invert-image
Drug.image2
Cholecalciferol-vitamin-D3-from-xtal-3D-sticks.png
Drug.image_class2
bg-transparent
Drug.DailyMedID
Cholecalciferol
Drug.routes_of_administration
By mouth, intramuscular
Drug.ATC_prefix
A11
Drug.ATC_suffix
CC05
Drug.legal_CA
Rx-only
Drug.legal_US
OTC
Drug.CAS_number
67-97-0
Drug.PubChem
5280795
Drug.DrugBank
DB00169
Drug.ChemSpiderID
4444353
Drug.UNII
1C6V77QF41
Drug.KEGG
C05443
Drug.ChEBI
28940

via Wikipedia infobox

Chemical data

Formula
C27H44O
Molecular weight
384.6 g/mol
IUPAC name
(1S,3Z)-3-[(2E)-2-[(1R,3aS,7aR)-7a-methyl-1-[(2R)-6-methylheptan-2-yl]-2,3,3a,5,6,7-hexahydro-1H-inden-4-ylidene]ethylidene]-4-methylidenecyclohexan-1-ol
SMILES
C[C@H](CCCC(C)C)[C@H]1CC[C@@H]\2[C@@]1(CCC/C2=C\C=C/3\C[C@H](CCC3=C)O)C
InChIKey
QYSXJUFSXHHAJI-YRZJJWOYSA-N
XLogP
7.9
Polar surface area
20.2 Ų
H-bond donors
1
H-bond acceptors
1
Formal charge
0

via PubChem

Research

32,107 papers

via PubMed

~13 min read

Encyclopedic overview

13 sections
Contents
  • Medical uses
  • Vitamin D deficiency
  • Other diseases
  • Biochemistry
  • Structure
  • Mechanism of action
  • Biosynthesis
  • Industrial production
  • Stability
  • Pesticide
  • See also
  • References
  • External links

Cholecalciferol, also known as vitamin D3, colecalciferol or calciol, is a skin-made vitamin D that is found in certain foods and used as a dietary supplement. It was first described in 1936, and is on the World Health Organization's List of Essential Medicines. In 2023, it was the 68th most commonly prescribed medication in the United States, with more than 9million prescriptions, and is available as a generic medication.

Cholecalciferol is synthesised in the skin following sunlight exposure. It is then converted in the liver to calcifediol (25-hydroxycholecalciferol D), which is further converted in the kidney to calcitriol (1,25-dihydroxycholecalciferol D). One of calcitriol's most important functions is to promote calcium uptake by the intestines. Cholecalciferol is present in food such as fatty fish, beef liver, eggs, and cheese. In some countries, cholecalciferol is also added to products like plants, cow milk, fruit juice, yogurt, and margarine.

Excerpted from Wikipedia’s “cholecalciferol” article, available under the CC BY-SA 4.0 licence.

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