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glycolaldehyde

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glycolaldehyde

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Also known as glycollaldehyde, Glycolic aldehyde, Methylol formaldehyde, Monomethylolformaldehyde, GLYCOALDEHYDE, 2-hydroxyacetaldehyde, 2-hydroxyethanal

Glycolaldehyde is the organic compound with the formula . It is the smallest possible molecule that contains both an aldehyde group () and a hydroxyl group (). It is a highly reactive molecule that occurs both in the biosphere and in the interstellar medium. It is normally supplied as a white solid. Although it conforms to the general formula for carbohydrates, , it is not generally considered to be a saccharide.

Chemical data

Formula
C2H4O2
Molecular weight
60.05 g/mol
IUPAC name
2-hydroxyacetaldehyde
SMILES
C(C=O)O
InChIKey
WGCNASOHLSPBMP-UHFFFAOYSA-N
XLogP
-0.9
Polar surface area
37.3 Ų
H-bond donors
1
H-bond acceptors
2
Formal charge
0

via PubChem

Wikidata facts

Mass
60.021129
Show 3 more facts
Commons category
Glycolaldehyde
canonical SMILES
C(C=O)O
chemical formula
C₂H₄O₂
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Article

9 sections
Contents
  • Structure
  • Synthesis
  • Biosynthesis
  • Role in formose reaction
  • Theorized role in abiogenesis
  • Formation in space
  • Detection in space
  • References
  • External links

Glycolaldehyde is the organic compound with the formula . It is the smallest possible molecule that contains both an aldehyde group () and a hydroxyl group (). It is a highly reactive molecule that occurs both in the biosphere and in the interstellar medium. It is normally supplied as a white solid. Although it conforms to the general formula for carbohydrates, {{chem2|C_{n}(H2O)_{n} }}, it is not generally considered to be a saccharide.

==Structure== Glycolaldehyde as a gas is a simple monomeric structure. As a solid and molten liquid, it exists as a dimer. Collins and George reported the equilibrium of glycolaldehyde in water by using NMR. In aqueous solution, it exists as a mixture of at least four species, which rapidly interconvert. thumb|380px|center|Structures and distribution of glycolaldehyde as a 20% solution in water. Notice that the free aldehyde is a minor component.

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