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hafnium

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Also known as Hf, element 72, 72Hf

Hafnium is a chemical element; it has symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1922, by Dirk Coster and George de Hevesy. Hafnium is named after , the Latin name for Copenhagen, where it was discovered. The element is obtained only by separation from zirconium, with most of the world's hafnium production coming from processes that also produce zirconium. These processes make use

AI overview

Hafnium is a rare silvery-gray metal that was predicted to exist by chemist Dmitri Mendeleev in 1869 but wasn't actually discovered until 1922. It is closely related to the metal zirconium and is extracted from zirconium minerals, making it an uncommon element that is produced mainly as a byproduct of zirconium processing.

AI-generated from the Wikipedia summary — may contain errors.

Chemical data

Formula
Hf
Molecular weight
178.49 g/mol
IUPAC name
hafnium
SMILES
[Hf]
InChIKey
VBJZVLUMGGDVMO-UHFFFAOYSA-N
Polar surface area
0 Ų
H-bond donors
0
H-bond acceptors
0
Formal charge
0

via PubChem

Research

1,753 papers

via PubMed

Wikidata facts

Mass
178.486
Image
Hf-crystal bar.jpg
Show 19 more facts
element symbol
Hf
Commons category
Hafnium
atomic number
72
NIOSH Pocket Guide ID
0309
density
13
immediately dangerous to life or health
50
Commons gallery
Hafnium
melting point
4041
boiling point
8316
vapor pressure
0
time-weighted average exposure limit
0.5
canonical SMILES
[Hf]
chemical formula
Hf
time of discovery or invention
1922-00-00
electronegativity
1
Unicode character
ionic radius
0.83
oxidation state
4
electron configuration
[Xe] 4f¹⁴ 5d² 6s²
Sources (7)

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~23 min read

Article

18 sections
Contents
  • Characteristics
  • Physical characteristics
  • Chemical characteristics
  • Isotopes
  • Occurrence
  • Production
  • Chemical compounds
  • History
  • Applications
  • Nuclear reactors
  • Alloys
  • Microprocessors
  • Isotope geochemistry
  • Other uses
  • Toxicity and safety
  • References
  • Further reading
  • External links

Hafnium is a chemical element; it has symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1922, by Dirk Coster and George de Hevesy. Hafnium is named after , the Latin name for Copenhagen, where it was discovered. The element is obtained only by separation from zirconium, with most of the world's hafnium production coming from processes that also produce zirconium. These processes make use of heavy mineral sands ore deposits, which include the minerals zircon, rutile, and ilmenite, among others.

Hafnium is most often used in alloys with nickel, and was used in larger quantities to produce the control rods used in nuclear reactors. Hafnium's large neutron capture cross section makes it a good material for neutron absorption in control rods in nuclear power plants, but at the same time requires that it be removed from the neutron-transparent corrosion-resistant zirconium alloys used in nuclear reactors. It is ductile, and is also used in filaments and electrodes. Some semiconductor fabrication processes use its oxide for integrated circuits at and smaller, and superalloys used for special applications can contain hafnium in combination with niobium, titanium, or tungsten.

Gallery (26)

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