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hafnium
Sign in to saveAlso known as Hf, element 72, 72Hf
Hafnium is a chemical element; it has symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1922, by Dirk Coster and George de Hevesy. Hafnium is named after , the Latin name for Copenhagen, where it was discovered. The element is obtained only by separation from zirconium, with most of the world's hafnium production coming from processes that also produce zirconium. These processes make use
OverviewAI-generated
Hafnium is a chemical element with the symbol Hf and atomic number 72. It has a mass of 178.486 and an electronegativity of 1. The element typically exhibits an oxidation state of 4 and an ionic radius of 0.83. Its electron configuration is [Xe] 4f¹⁴ 5d² 6s².
The substance has a density of 13, a melting point of 4041, and a boiling point of 8316. Its vapor pressure is 0. Hafnium was discovered in 1922. It is associated with the Commons category "Hafnium" and the Unicode character "鉿".
Exposure limits for the element include a time-weighted average of 0.5 and an immediately dangerous to life or health level of 50. The NIOSH Pocket Guide ID for hafnium is 0309. In chemical databases, it is identified by PubChem CID 23986 and has a molecular weight of 178.49.
Synthesized by Vinony from 32 facts across 4 sources: Wikidata, PubMed, PubChem, Vinony graph. Generated from structured data (not the Wikipedia text) and checked against those facts — may still contain errors.
Chemical data
- Formula
- Hf
- Molecular weight
- 178.49 g/mol
- IUPAC name
- hafnium
- SMILES
- [Hf]
- InChIKey
- VBJZVLUMGGDVMO-UHFFFAOYSA-N
- Polar surface area
- 0 Ų
- H-bond donors
- 0
- H-bond acceptors
- 0
- Formal charge
- 0
via PubChem
Research
1,753 papers- Advances of hafnium based nanomaterials for cancer theranostics.Frontiers in chemistry · 2023
- Harnessing Hafnium-Based Nanomaterials for Cancer Diagnosis and Therapy.Small (Weinheim an der Bergstrasse, Germany) · 2023
- Synthesis and Bioapplication of Emerging Nanomaterials of Hafnium.ACS nano · 2024
- Use of hafnium(IV) oxide in biosensors.Journal of immunoassay & immunochemistry · 2018
- Carbides and Nitrides of Zirconium and Hafnium.Materials (Basel, Switzerland) · 2019
via PubMed
Wikidata facts
- Instance of
- lithophile
- Subclass of
- transition metal
- Part of
- period 6
- Named after
- Copenhagen
- Mass
- 178.486
- Image
- Hf-crystal bar.jpg
Show 23 more facts
- element symbol
- Hf
- Commons category
- Hafnium
- topic's main category
- Category:Hafnium
- atomic number
- 72
- NIOSH Pocket Guide ID
- 0309
- density
- 13
- immediately dangerous to life or health
- 50
- Commons gallery
- Hafnium
- melting point
- 4041
- boiling point
- 8316
- vapor pressure
- 0
- time-weighted average exposure limit
- 0.5
- canonical SMILES
- [Hf]
- chemical formula
- Hf
- time of discovery or invention
- 1922-00-00
- discoverer or inventor
- Dirk Coster
- electronegativity
- 1
- location of discovery
- Denmark
- Unicode character
- 鉿
- ionic radius
- 0.83
- oxidation state
- 4
- electron configuration
- [Xe] 4f¹⁴ 5d² 6s²
- on focus list of Wikimedia project
- Wikipedia:Vital articles/Level/4
Sources (7)
via Wikidata · CC0
~23 min read
Encyclopedic overview
18 sectionsContents
- Characteristics
- Physical characteristics
- Chemical characteristics
- Isotopes
- Occurrence
- Production
- Chemical compounds
- History
- Applications
- Nuclear reactors
- Alloys
- Microprocessors
- Isotope geochemistry
- Other uses
- Toxicity and safety
- References
- Further reading
- External links
Hafnium is a chemical element; it has symbol Hf and atomic number 72. A lustrous, silvery gray, tetravalent transition metal, hafnium chemically resembles zirconium and is found in many zirconium minerals. Its existence was predicted by Dmitri Mendeleev in 1869, though it was not identified until 1922, by Dirk Coster and George de Hevesy. Hafnium is named after , the Latin name for Copenhagen, where it was discovered. The element is obtained only by separation from zirconium, with most of the world's hafnium production coming from processes that also produce zirconium. These processes make use of heavy mineral sands ore deposits, which include the minerals zircon, rutile, and ilmenite, among others.
Hafnium is most often used in alloys with nickel, and was used in larger quantities to produce the control rods used in nuclear reactors. Hafnium's large neutron capture cross section makes it a good material for neutron absorption in control rods in nuclear power plants, but at the same time requires that it be removed from the neutron-transparent corrosion-resistant zirconium alloys used in nuclear reactors. It is ductile, and is also used in filaments and electrodes. Some semiconductor fabrication processes use its oxide for integrated circuits at and smaller, and superalloys used for special applications can contain hafnium in combination with niobium, titanium, or tungsten.
Excerpted from Wikipedia’s “hafnium” article, available under the CC BY-SA 4.0 licence.
Gallery (26)
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