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adamantane

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adamantane

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Adamantane is an organic compound with formula C10H16 or, more descriptively, (CH)4(CH2)6. Adamantane molecules can be described as the fusion of three cyclohexane rings. The molecule is both rigid and virtually strain-free. Adamantane is the most stable isomer of C10H16. The spatial arrangement of carbon atoms in the adamantane molecule is the same as in the diamond crystal. This similarity led to the name adamantane, which is derived from the Greek adamantinos (relating to steel or diamond). It is a white solid with a camphor-like odor. It is the simplest diamondoid.

Chemical data

Formula
C10H16
Molecular weight
136.23 g/mol
IUPAC name
adamantane
SMILES
C1C2CC3CC1CC(C2)C3
InChIKey
ORILYTVJVMAKLC-UHFFFAOYSA-N
XLogP
3.8
Polar surface area
0 Ų
H-bond donors
0
H-bond acceptors
0
Formal charge
0

via PubChem

Wikidata facts

Mass
136.125
Show 6 more facts
canonical SMILES
C1C2CC3CC1CC(C2)C3
Commons category
Adamantane
chemical formula
C₁₀H₁₆
melting point
267
standard enthalpy of formation
-197.2
refractive index
1.568
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Article

18 sections
Contents
  • History and synthesis
  • Natural occurrence
  • Physical properties
  • Structure
  • Hardness
  • Spectroscopy
  • Optical activity
  • Nomenclature
  • Chemical properties
  • Bridgehead reactions
  • Substitution at bridging carbons
  • Uses
  • In medicine
  • In designer drugs
  • Spacecraft propellant
  • Potential technological applications
  • Adamantane analogues
  • References

Adamantane is an organic compound with formula C10H16 or, more descriptively, (CH)4(CH2)6. Adamantane molecules can be described as the fusion of three cyclohexane rings. The molecule is both rigid and virtually strain-free. Adamantane is the most stable isomer of C10H16. The spatial arrangement of carbon atoms in the adamantane molecule is the same as in the diamond crystal. This similarity led to the name adamantane, which is derived from the Greek adamantinos (relating to steel or diamond). It is a white solid with a camphor-like odor. It is the simplest diamondoid.

The discovery of adamantane in petroleum in 1933 launched a new field of chemistry dedicated to the synthesis and properties of polyhedral organic compounds. Adamantane derivatives have found practical application as drugs, polymeric materials, and thermally stable lubricants.

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