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Adamantanone

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Adamantanone is the ketone of adamantane. A white solid, it is prepared by oxidation of adamantane. It is a precursor to several adamantane derivatives.

Wikidata facts

Has part
hydrogen
Mass
150.104462
Show 2 more facts
canonical SMILES
C1C2CC3CC1CC(C2)C3=O
chemical formula
C₁₀H₁₄O
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Encyclopedic overview

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Adamantanone is the ketone of adamantane. A white solid, it is prepared by oxidation of adamantane. It is a precursor to several adamantane derivatives.

Adamantanone and some related polycyclic ketones, are reluctant to form enolates. This barrier arises because the resulting carbanion cannot exist in conjugation with the carbonyl pi-bond.

Excerpted from Wikipedia’s “Adamantanone” article, available under the CC BY-SA 4.0 licence.

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