チオアミド
Sign in to saveAlso known as thioamides, thionamide, thiourylene
thumb|right|150px|class=skin-invert-image|General structure of a thioamide A thioamide (rarely, thionamide, but also known as thiourylenes) is a functional group with the general structure , where are any groups (typically organyl groups or hydrogen). Analogous to amides, thioamides exhibit greater multiple bond character along the C-N bond, resulting in a larger rotational barrier.
Research
3,549 papers- Ynamide-Mediated Thioamide and Primary Thioamide Syntheses.The Journal of organic chemistry · 2022
- Thioamide Analogues of MHC I Antigen Peptides.Journal of the American Chemical Society · 2023
- Thioamide-based fluorescent sensors for dipeptidyl peptidase 4.Chemical communications (Cambridge, England) · 2024
- Backbone thioamide directed macrocyclisation: lactam stapling of peptides.Organic & biomolecular chemistry · 2022
- Construction of Thioamide Peptides from Chiral Amino Acids.Angewandte Chemie (International ed. in English) · 2023
via PubMed
Wikidata facts
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- Commons category
- Thioamides
- topic's main category
- Category:Thioamides
Sources (2)
via Wikidata · CC0
Article · 日本語
チオアミド (thioamide) は、有機化学において R−C(=S)−NR1R2 の構造の官能基（チオアミド基）、あるいはチオアミド基を有する有機化合物群のを指す呼称である。通常のカルボン酸アミドのカルボニル酸素を硫黄原子に置き換えたもの。同じ C=S 二重結合を持つチオケトンやチオアルデヒドが一般に不安定なのに対し、チオアミドは多くの場合安定な化合物である。
Abstract from DBpedia / Wikipedia · CC BY-SA