Also known as triisobutylaluminium
Triisobutylaluminium (TiBA) is an organoaluminium compound with the formula Al(CH2CH(CH3)2)3. This colorless pyrophoric liquid is mainly used to make linear primary alcohols and α-olefins.
Triisobutylaluminium (TiBA) is an organoaluminium compound with the formula Al(CH2CH(CH3)2)3. This colorless pyrophoric liquid is mainly used to make linear primary alcohols and α-olefins.
==Structure== Triisobutylaluminium exists in equilibrium with its dimer. The equilibrium constant, KD, is 3.810 at 20 °C. 2Al(CH2CH(CH3)2)3 [Al(CH2CH(CH3)2)3]2 In the dimer, the bridging carbon-aluminium bond is elongated and exhibits evidence of restricted rotation. For the sake of simplicity, TiBA is written as the monomer in this article.
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