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cyanocobalamin

Structure via PubChem · Public domain (PubChem)

EntityQ252251· pop 33· linked from 285 articles

cyanocobalamin

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Also known as Vitamin B 12, Rubivite, Rubramin, Nascobal, Calomist, Ruvite, Berubigen

Cyanocobalamin is a form of vitamin used to treat and prevent vitamin deficiency except in the presence of cyanide toxicity. The deficiency may occur in pernicious anemia, following surgical removal of the stomach, with fish tapeworm, or due to bowel cancer. It is given by mouth, by injection into a muscle, or as a nasal spray.

Key facts

Drug.solubility
1/80
Drug.sol_units
g/ml
Drug.image
Cyanocobalamin-b12.png
Drug.image_class
skin-invert-image
Drug.caption
Skeletal formula
Drug.image2
Cyanocobalamin-from-xtal-3D-st-noH.png
Drug.image_class2
bg-transparent
Drug.caption2
Stick model of cyanocobalamin based on the crystal structure
Drug.pronounce
sye AN oh koe BAL a min
Drug.tradename
Cobolin-M, Depo-Cobolin, others
Drug.MedlinePlus
a604029
Drug.DailyMedID
Cyanocobalamin
Drug.pregnancy_AU_comment
Exempt
Drug.routes_of_administration
By mouth, intramuscular, nasal spray
Drug.ATC_prefix
B03
Drug.ATC_suffix
BA01
Drug.legal_US
OTC
Drug.legal_US_comment
/ Rx-only

via Wikipedia infobox

Chemical data

Formula
C63H88CoN14O14P
Molecular weight
1355.4 g/mol
IUPAC name
cobalt(3+);[(2R,3S,4R,5S)-5-(5,6-dimethylbenzimidazol-1-yl)-4-hydroxy-2-(hydroxymethyl)oxolan-3-yl] [(2R)-1-[3-[(2R,3R,5Z,7S,9Z,12S,13S,14Z,17S,18S,19R)-2,13,18-tris(2-amino-2-oxoethyl)-7,12,17-tris(3-amino-3-oxopropyl)-3,5,8,8,13,15,18,19-octamethyl-2,7,12,17-tetrahydro-1H-corrin-22-id-3-yl]propanoylamino]propan-2-yl] phosphate;cyanide
SMILES
CC1=CC2=C(C=C1C)N(C=N2)[C@@H]3[C@@H]([C@@H]([C@H](O3)CO)OP(=O)([O-])O[C@H](C)CNC(=O)CC[C@@]4([C@H](C5[C@]6([C@@]([C@@H](C(=N6)/C(=C\7/[C@@]([C@@H](C(=N7)/C=C\8/C([C@@H](/C(=C(/C4=N5)\C)/[N-]8)CCC(=O)N)(C)C)CCC(=O)N)(C)CC(=O)N)/C)CCC(=O)N)(C)CC(=O)N)C)CC(=O)N)C)O.[C-]#N.[Co+3]
InChIKey
FDJOLVPMNUYSCM-UVKKECPRSA-L
Polar surface area
476 Ų
H-bond donors
9
H-bond acceptors
21
Formal charge
0

via PubChem

Research

31,187 papers

via PubMed

Wikidata facts

Subclass of
cobalamin
Has part
phosphorus
Mass
1354.567
Has use
medication
Show 9 more facts
canonical SMILES
CC1=CC2=C(C=C1C)N(C=N2)C3C(C(C(O3)CO)OP(=O)([O-])OC(C)CNC(=O)CCC4(C(C5C6(C(C(C(=C(C7=NC(=CC8=NC(=C(C4=N5)C)C(C8(C)C)CCC(=O)N)C(C7(C)CC(=O)N)CCC(=O)N)C)[N-]6)CCC(=O)N)(C)CC(=O)N)C)CC(=O)N)C)O.[C-]#N.[Co+3]
chemical formula
C₆₃H₈₈CoN₁₄O₁₄P
isomeric SMILES
[Co+3].[C-]#N.C[C@H](CNC(=O)CC[C@]1(C)[C@@H](CC(N)=O)C2[N-]C1=C(C)C3=NC(=CC4=NC(=C(C)C5=N[C@]2(C)[C@@](C)(CC(N)=O)[C@@H]5CCC(N)=O)[C@@](C)(CC(N)=O)[C@@H]4CCC(N)=O)C(C)(C)[C@@H]3CCC(N)=O)OP([O-])(=O)O[C@@H]6[C@@H](CO)O[C@@H]([C@@H]6O)N7C=NC8=C7C=C(C)C(C)=C8
Commons category
Cyanocobalamin
different from
vitamin B12
medical condition treated
pernicious anemia
NCI Thesaurus ID
C64333
subject has role
vitamin B
defined daily dose
1
Sources (4)

via Wikidata · CC0

~11 min read

Encyclopedic overview

12 sections
Contents
  • Medical use
  • Use in food
  • Side effects
  • Chemistry
  • Chemical reactions
  • Production
  • Metabolism
  • In the cytosol
  • In mitochondria
  • Absorption and transport
  • See also
  • References

Cyanocobalamin is a form of vitamin used to treat and prevent vitamin deficiency except in the presence of cyanide toxicity. The deficiency may occur in pernicious anemia, following surgical removal of the stomach, with fish tapeworm, or due to bowel cancer. It is given by mouth, by injection into a muscle, or as a nasal spray.

Cyanocobalamin is generally well tolerated. Minor side effects may include diarrhea, nausea, upset stomach, and itchiness. Serious side effects may include anaphylaxis, and low blood potassium resulting in heart failure. Use is not recommended in those who are allergic to cobalt or have Leber's disease. No overdosage or toxicity has been reported. It is less preferred than hydroxocobalamin for treating vitamin deficiency because it has a slightly lower bioavailability. Some studies have shown it to possess an antihypotensive effect. Vitamin is an essential nutrient meaning that it cannot be made by the body but is required for life.

Excerpted from Wikipedia’s “cyanocobalamin” article, available under the CC BY-SA 4.0 licence.

Gallery (3)