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pinacol

Structure via PubChem · Public domain (PubChem)

EntityQ421634· pop 23· linked from 19 articles

Also known as Tetramethylethylene glycol, 1,1,2,2-Tetramethylethylene glycol, 2,3-Dimethyl-2,3-butanediol, 2,3-Dimethyl-2,3-dihydroxybutane, 2,3-Dihydroxy-2,3-dimethylbutane, 2,3-dimethylbutane-2,3-diol

Pinacol is a branched alcohol which finds use in organic syntheses. It is a diol that has hydroxyl groups on vicinal carbon atoms. A white solid that melts just above room temperature, pinacol is notable for undergoing the pinacol rearrangement in the presence of acid and for being the namesake of the pinacol coupling reaction.

Chemical data

Formula
C6H14O2
Molecular weight
118.17 g/mol
IUPAC name
2,3-dimethylbutane-2,3-diol
SMILES
CC(C)(C(C)(C)O)O
InChIKey
IVDFJHOHABJVEH-UHFFFAOYSA-N
XLogP
0.1
Polar surface area
40.5 Ų
H-bond donors
2
H-bond acceptors
2
Formal charge
0

via PubChem

Wikidata facts

Mass
118.099
Show 4 more facts
chemical formula
C₆H₁₄O₂
Commons category
Pinacol
canonical SMILES
CC(C)(C(C)(C)O)O
melting point
44.0
Sources (3)

via Wikidata · CC0

~1 min read

Article

4 sections
Contents
  • Preparation
  • Reactions
  • See also
  • References

Pinacol is a branched alcohol which finds use in organic syntheses. It is a diol that has hydroxyl groups on vicinal carbon atoms. A white solid that melts just above room temperature, pinacol is notable for undergoing the pinacol rearrangement in the presence of acid and for being the namesake of the pinacol coupling reaction.

==Preparation== It may be produced by the pinacol coupling reaction from acetone:

Gallery (3)

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