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alloxan

Structure via PubChem · Public domain (PubChem)

EntityQ417701· pop 22· linked from 29 articles

Also known as NSC 7169, 5,6-dioxouracil, 5-oxobarbituric acid, 2,4,5,6-pyrimidinetetrone, pyrimidinetetrone, 2,4,5,6(1H,3H)-pyrimidinetetrone, alloxane, 2,4,5,6-tetraoxohexahydropyrimidine

Alloxan, sometimes referred to as alloxan monohydrate, is an organic compound with the formula . It is classified as a derivative of pyrimidine. The anhydrous derivative is also known, as well as a dimeric derivative. These are some of the earliest known organic compounds. They exhibit a variety of biological activities.

Chemical data

Formula
C4H2N2O4
Molecular weight
142.07 g/mol
IUPAC name
1,3-diazinane-2,4,5,6-tetrone
SMILES
C1(=O)C(=O)NC(=O)NC1=O
InChIKey
HIMXGTXNXJYFGB-UHFFFAOYSA-N
XLogP
-1
Polar surface area
92.3 Ų
H-bond donors
2
H-bond acceptors
4
Formal charge
0

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Wikidata facts

Mass
142.001
Show 3 more facts
Commons category
Alloxan
chemical formula
C₄H₂N₂O₄
canonical SMILES
C1(=O)C(=O)NC(=O)NC1=O
Sources (3)

via Wikidata · CC0

~5 min read

Article

11 sections
Contents
  • History and literature
  • Synthesis
  • Reactions
  • Hydrolysis
  • Reduction
  • Biological effects
  • Reactive oxygen species generation
  • Impact upon beta cells
  • See also
  • References
  • External links

Alloxan, sometimes referred to as alloxan monohydrate, is an organic compound with the formula . It is classified as a derivative of pyrimidine. The anhydrous derivative is also known, as well as a dimeric derivative. These are some of the earliest known organic compounds. They exhibit a variety of biological activities.

==History and literature== The compound was discovered by Justus von Liebig and Friedrich Wöhler. It is one of the oldest named organic compounds. It was originally prepared in 1818 by Luigi Valentino Brugnatelli (1761-1818) and was named in 1838 by Wöhler and Liebig. The name "Alloxan" emerged from an amalgamation of the words "Allantoïn" and "Oxalsäure" (oxalic acid). The alloxan model of diabetes was first described in rabbits by Dunn, Sheehan, and McLetchie in 1943. The name is derived from allantoin, a product of uric acid excreted by the fetus into the allantois, and oxaluric acid derived from oxalic acid and urea, found in urine.

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