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dichlorosilane

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dichlorosilane

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Dichlorosilane, or DCS as it is commonly known, is a chemical compound with the formula H2SiCl2. In its major use, it is mixed with ammonia (NH3) in LPCVD chambers to grow silicon nitride in semiconductor processing. A higher concentration of DCS·NH3 (i.e. 16:1), usually results in lower stress nitride films.

Chemical data

Formula
Cl2H2Si
Molecular weight
101 g/mol
IUPAC name
dichlorosilane
SMILES
[SiH2](Cl)Cl
InChIKey
MROCJMGDEKINLD-UHFFFAOYSA-N
Polar surface area
0 Ų
H-bond donors
0
H-bond acceptors
0
Formal charge
0

via PubChem

Wikidata facts

Mass
99.930282
Show 7 more facts
electric dipole moment
1.17
boiling point
8.3
chemical formula
Cl₂H₂Si
Commons category
Dichlorosilane
canonical SMILES
[SiH2](Cl)Cl
ionization energy
11.40
melting point
-122
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Article

9 sections
Contents
  • History
  • Reactions and formation
  • Hydrolysis
  • Decomposition
  • Ultrapurification
  • Advantage of use
  • Safety hazards
  • References
  • External links

Dichlorosilane, or DCS as it is commonly known, is a chemical compound with the formula H2SiCl2. In its major use, it is mixed with ammonia (NH3) in LPCVD chambers to grow silicon nitride in semiconductor processing. A higher concentration of DCS·NH3 (i.e. 16:1), usually results in lower stress nitride films.

==History== Dichlorosilane was originally prepared by Stock and Somieski by the reaction of SiH4 with hydrogen chloride. Dichlorosilane reacts with water vapor to initially give monomeric prosiloxane: Monomeric polymerizes rapidly upon condensation or in solution.

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