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polyisobutene

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Also known as PIB, poly(isobutylene), polyisobutylene

Polyisobutene (polyisobutylene) is a class of organic polymers prepared by polymerization of isobutene. The polymers often have the formula Me3C[CH2CMe2]nH (Me = CH3). They are typically colorless gummy solids.

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Polyisobutene (polyisobutylene) is a class of organic polymers prepared by polymerization of isobutene. The polymers often have the formula Me3C[CH2CMe2]nH (Me = CH3). They are typically colorless gummy solids.

Cationic polymerization, initiated with a strong Brønsted or Lewis acid, is the typical method for its production. The molecular weight (MW) of the resulting polymer determines the applications. Low MW polyisobutene, a mixture of oligomers with Mns of about 500, is used as plasticizers. Medium and high MW polyisobutenes, with Mn ≥ 20,000, are components of commercial adhesives.

Excerpted from Wikipedia’s “polyisobutene” article, available under the CC BY-SA 4.0 licence.