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N-methylphenethylamine

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Also known as NMPEA

'''N-Methylphenethylamine (NMPEA''') is a naturally occurring trace amine neuromodulator in humans that is derived from the trace amine, phenethylamine (PEA). It has been detected in human urine (<1&nbsp;μg over 24&nbsp;hours) and is produced by phenylethanolamine N-methyltransferase with phenethylamine as a substrate, which significantly increases PEA's effects. PEA breaks down into phenylacetaldehyde which is further broken down into phenylacetic acid by monoamine oxidase. When this is inhibited by monoamine oxidase inhibitors, it allows more of the PEA to remain present and produce psychoac

Key facts

Drug.verifiedrevid
415845541
Drug.drug_name
N-Methylphenethylamine
Drug.image
N-Methylphenethylamine.svg
Drug.image_class
skin-invert-image
Drug.width
200px
Drug.image2
N-Methylphenethylamine_3D_Structure_Xtal.png
Drug.image_class2
bg-transparent
Drug.width2
235px
Drug.legal_CA
Schedule 1 as an isomer of amphetamine
Drug.CAS_number
589-08-2
Drug.PubChem
11503
Drug.ChemSpiderID
11019
Drug.UNII
02N4V81704
Drug.ChEMBL
45763
Drug.synonyms
NMPEA; N-Methyl-2-phenylethanamine; N-Methylphenethylamine; N-Methyl-β-phenethylamine
Drug.IUPAC_name
N-methyl-2-phenylethan-1-amine
Drug.C
9
Drug.H
13

via Wikipedia infobox

Wikidata facts

Mass
135.105
Show 4 more facts
found in taxon
Senegalia berlandieri
chemical formula
C₉H₁₃N
canonical SMILES
CNCCC1=CC=CC=C1
Commons category
N-Methylphenethylamine
Sources (2)

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Encyclopedic overview

5 sections
Contents
  • Biosynthesis
  • Chemistry
  • Pharmacology
  • Toxicology
  • References

'''N-Methylphenethylamine (NMPEA''') is a naturally occurring trace amine neuromodulator in humans that is derived from the trace amine, phenethylamine (PEA). It has been detected in human urine (a = 10.14; pKb = 3.86 (calculated from data given as Kb). It forms a hydrochloride salt, m.p.&nbsp;162–164&nbsp;°C.

Although NMPEA is available commercially, it may be synthesized by various methods. An early synthesis reported by Carothers and co-workers involved conversion of phenethylamine to its p-toluenesulfonamide, followed by N-methylation using methyl iodide, then hydrolysis of the sulfonamide. A more recent method, similar in principle, and used for making NMPEA radio-labeled with 14C in the N-methyl group, started with the conversion of phenethylamine to its trifluoroacetamide. This was N-methylated (in this particular case using 14C – labeled methyl iodide), and then the amide hydrolyzed.

Excerpted from Wikipedia’s “N-methylphenethylamine” article, available under the CC BY-SA 4.0 licence.

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